課程介紹
Kinetics of Materials
Kinetics of Materials — 114-2 Elective / Core (3.0 credits).
✦ Course Information
| Course title | Kinetics of Materials |
|---|---|
| Semester | 114-2 |
| Designated for | Materials Science and Engineering |
| Curriculum Number | MSE5063 |
| Curriculum Identity Number | MSE5063 |
| Class | — |
| Credits | 3.0 |
| Full / Half Yr. | Half |
| Required / Elective | Elective / Core |
| Remarks | Ceiba Web Server |
為確保您我的權利,請尊重智慧財產權及不得非法影印。
Class Section
| Class | Instructor | Time | Location |
|---|---|---|---|
| — | Te-Cheng Su | 09:20–12:10, each Friday | — |
Course Description
Kinetics of Materials, one of the fundamental courses in NTU-MSE graduate school, teaches how to calculate the transport of different types of atoms and ions in materials through basic diffusion equations and reaction equations. We will focus on the analytical approaches for predicting the transient behavior of substances under various initial and boundary conditions. There is a wide range of applications of the Kinetics of Materials in the materials processing control, such as heat treatment, surface modification, doping of semiconductor components, production of conductive ceramics, and surface chemical reactions of various materials. However, the transient equations involved and the required calculation skills will become more complex. Therefore, the aim of the Kinetics of Materials course is: after reading the lecture notes, checking equations derived on the fancy electronic whiteboard, realizing how to solve example kinetics questions, and reviewing the recorded videos in NTU COOL, you will be able to utilize various kinetic equations and models while facing related kinetics problems, and accurately grasp the mass transfer and reaction issues in the materials processing system in the future.
Course Objective
The overall objectives of this course are to:
- offer an overview of main kinetics theories such as Fick's laws, Peclet number, steady state, stochastic process, reaction rate law, Arrhenius equation, and ionic defect structure.
- introduce how we can apply those physical laws to real systems through some mathematical tools such as tensor, Laplace transform, superposition principle, Fourier series, probability distribution functions, and linearized diagrams.
- emphasize the outcomes of the competition between diffusion and reaction.
Course Requirement
Students should have taken the following MSE undergraduate courses (or other equivalent courses):
- Physical Metallurgy (I and II), Curriculum Number MSE2004 and MSE2005
- Engineering Mathematics (I and II), Curriculum Number MSE2002 and MSE2003
- Student Workload (Expected weekly study hours before and/or after class): —
- Office Hours: use NTU COOL Conversations first
- Designated reading:
- M.E. Glicksman, Diffusion in Solids: Field Theory, Solid-State Principles, and Applications, John Wiley & Sons, Inc., 2000. (01 – 12, Glicksman)
- K.J. Laidler, Chemical Kinetics, 3rd ed., Harper & Row, New York, 1987. (13 & 14, Laidler)
- H. I. Yoo, Lectures on Kinetic Processes in Materials. Springer, https://doi.org/10.1007/978-3-030-25950-1 (part of 15, Yoo)
- M.G. Fontana, Corrosion engineering, 3rd ed., McGraw-Hill, New York, 1986. (16, Fontana)
- Y.M. Chiang, D. Birnie III, W.D. Kingery, Physical Ceramics, Principles for Ceramic Science and Engineering, John Wiley & Sons, Inc., 1997. (17 & 18, Chiang)
References
J. Crank, Mathematics of Diffusion, Oxford Science Publications, 2nd ed. 1992.
W.D. Kingery, Introduction to Ceramics, John Wiley & Sons, Inc., 1976.
D.A. Porter and K.E. Easterling, Phase Transformations in Metals and Alloys 2nd ed., Chapman & Hall, 1992.
R.W. Balluffi, S.M. Allen, W.C. Carter, Kinetics of Materials, John Wiley & Sons, Inc., 2005.
O. Levenspiel, Chemical Reaction Engineering, John Wiley, 3rd ed. 1999.
Grading
| No. | Item | % | Explanations for the conditions |
|---|---|---|---|
| 1 | Midterm #1 | 50% | 50% Close + 50% Open |
| 2 | Final exam | 50% | 50% Close + 50% Open |
Progress
| Week | Date | Topic |
|---|---|---|
| Week 1 | 03/06 | Introduction to Kinetics (00) |
| Week 2 | 03/13 | Laws of Diffusion and Diffusion in Generalized Media (01 & 02, Glicksman) |
| Week 3 | 03/20 | Solutions to the Linear Diffusion Equation I: superposition principle (03 – 06, Glicksman) |
| Week 4 | 03/27 | Solutions to the Linear Diffusion Equation II: Fourier series (07 & 08, Glicksman) |
| Week 5 | 04/03 | Solutions to the Linear Diffusion Equation III: steady-state method (10 & 12, Glicksman) |
| Week 6 | 04/10 | Introduction to Chemical Kinetics I: basic concepts (13, Laidler) |
| Week 7 | 04/17 | Introduction to Chemical Kinetics II: analysis of kinetic results (14, Laidler) |
| Week 8 | 04/24 | Midterm examination (01 – 12 Glicksman and "13+" Laidler) |
| Week 9 | 05/01 | Flexible arrangement of discussions on Chemical Kinetics and Physical Chemistry |
| Week 10 | 05/08 | Adsorption and Evaporation (15, Yoo and others) |
| Week 11 | 05/15 | High-Temperature Oxidation I: mechanisms and kinetics (16, Fontana) |
| Week 12 | 05/22 | High-Temperature Oxidation II: high-temperature materials (16, Fontana) |
| Week 13 | 05/29 | Vacancy-Assisted Diffusion I: defects in ceramics (17, Chiang) |
| Week 14 | 06/05 | Vacancy-Assisted Diffusion II: defect equilibria (17, Chiang) |
| Week 15 | 06/12 | Vacancy-Assisted Diffusion III: mass transport behavior (18, Chiang) |
| Week 16 | 06/15 | Final examination (Mostly 13 – 18) |